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Crystallization

Crystallization

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Since the first publication of this definitive work nearly 40 years ago, this fourth edition has been completely rewritten. Crystallization is used at some stage in nearly all process industries as a method of production, purification or recovery of solid materials. Hoffman JD, Frolen LJ, Ross GS et al (1975) Growth-rate of spherulites and axialites from melt in polyethylene fractions—regime-1 and regime-2 crystallization. J Res Nat Bur Stan Sect A Phys Chem 79(6):671–699. https://doi.org/10.6028/jres.079A.026 Han R, Nie M, Wang Q (2015) Control over beta-form hybrid shish-kebab crystals in polypropylene pipe via coupled effect of self-assembly beta nucleating agent and rotation extrusion. J Taiwan Inst Chem Eng 52:158–164. https://doi.org/10.1016/j.jtice.2015.02.002 Koutsky JA, Walton AG, Baer E (1967) Nucleation of polymer droplets. J Appl Phys 38(4):1832–1839. https://doi.org/10.1063/1.1709769

Hoffman JD, Miller RL (1988) Test of the reptation concept—crystal-growth rate as a function of molecular-weight in polyethylene crystallized from the melt. Macromolecules 21(10):3038–3051. https://doi.org/10.1021/ma00188a024 Salt crystallisation is the most practical use of crystallisation, and it is also the most cost-effective technique to create salt today. Compound purification and crystal synthesis are two further uses for the technology. Water of crystallisation may alternatively be defined as the water molecules that make up a crystal’s structure. They form and crystallise the crystals. CuSO 4. 5H 2O (Copper sulphate) is an antibacterial and antifungal agent that may be used topically. Application of Crystallization:Crist B (2013) Structure of polycrystalline aggregates. In: Piorkowska R, Routledge G (ed) Handbook of polymer crystallization. Wiley, New Jersey, pp 73–124 Mezghani K, Phillips PJ (1994) Equilibrium melting-point of deuterated polypropylene. Macromolecules 27(21):6145–6146. https://doi.org/10.1021/ma00099a032 Wunderlich B (1973) Macromolecular physics. Crystal structure, morphology, defects, vol 1. Academic Press, New York, p 435 Varga J, Ehrenstein GW (1997) High-temperature hedritic crystallization of the beta-modification of isotactic polypropylene. Colloid Polym Sci 275(6):511–519. https://doi.org/10.1007/s003960050113

Xiao ZG, Sun Q, Xue G et al (2003) Thermal behavior of isotactic polypropylene freeze-extracted from solutions with varying concentrations. Eur Polymer J 39(5):927–931. https://doi.org/10.1016/s0014-3057(02)00313-0Supaphol P, Spruiell JE (2000) Regime crystallization in syndiotactic polypropylenes: re-evaluation of the literature data. Polymer 41(3):1205–1216. https://doi.org/10.1016/s0032-3861(99)00254-2

Li JX, Cheung WL (1999) RuO4 staining and lamellar structure of alpha- and beta-PP. J Appl Polym Sci 72(12):1529–1538. https://doi.org/10.1002/(sici)1097-4628(19990620)72:12%3c1529:Aid-app4%3e3.0.Co;2-u Zhang J, Yang D, Thierry A et al (2001) Isochiral form II of syndiotactic polypropylene produced by epitaxial crystallization. Macromolecules 34(18):6261–6267. https://doi.org/10.1021/ma010758i De Rosa C, Corradini P (1993) Crystal-structure of syndiotactic polypropylene. Macromolecules 26(21):5711–5718. https://doi.org/10.1021/ma00073a028 De Rosa C, Auriemma F, Vinti V (1998) On the form II of syndiotactic polypropylene. Macromolecules 31(21):7430–7435. https://doi.org/10.1021/ma980789m Rozanski A, Galeski A (2015) Crystalline lamellae fragmentation during drawing of polypropylene. Macromolecules 48(15):5310–5322. https://doi.org/10.1021/acs.macromol.5b01180

Galeski A (1994) Nucleation in polypropylene. In: J. Karger-Kocsis (ed) Polypropylene: structures, properties and blends. Chapman & Hall, London, pp 25–49 Xiao ZG, Sun N (2016) Crystallization behavior for metallocene-catalyzed isotactic polypropylene in alkane solvents of various molecular sizes. J Therm Anal Calorim 124(1):295–303. https://doi.org/10.1007/s10973-015-5146-3 Lotz B (2014) A new ε crystal modification found in stereodefective isotactic polypropylene samples. Macromolecules 47:7612–7624. https://doi.org/10.1021/ma5009868



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